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Dynamic Windows Based on Reversible Metal Electrodeposition with Enhanced Functionality
(Journal of The Electrochemical Society, 2019)
Electronically tintable windows increase the energy efficiency and comfort of buildings and automobiles. Recently, dynamic windows harnessing reversible metal electrodeposition have been explored as a viable alternative ...
Hydrogen Induced Abrupt Structural Expansion at High Temperatures of a Ni32Nb28Zr30Cu10 Membrane for H2 Purification
Ni-Nb-Zr amorphous membranes, prepared by melt-spinning, show great potential for replacing crystalline Pd-based materials in the field of hydrogen purification to an ultrapure grade (>99.999%). In this study, we ...
Diaquatris[4,4,4-trifluoro-3-oxo-1-(thiophen-2-yl)but-1-en-1-olato]neodymium(III) acetonitrile monosolvate
The title complex, [Nd(C8H4F3O2S)3(H2O)2]稢H3CN, consists of an NdIII ion surrounded by three 4,4,4-trifluoro-3-oxo-1-(thiophen-2-yl)but-1-en-1-olate ligands, coordinated through the O atoms, and two water mols. The Nd-O ...
Cadmium and Zinc Alloyed Cu-In-S Nanocrystals and Their Optical Properties
Cadmium (Cd)- and zinc (Zn)-alloyed copper杋ndium杝ulfide (Cu朓n朣 or CIS) nanocrystals (NCs) several nanometers in diameter were prepared using thermal decomposition methods, and the effects of Cd and Zn on optical properties, ...
Homobinuclear sulfato-bridged and mononuclear nitrato complexes of Cu(II) with thiophen-2-yl-dipicolylamine; structure and anion-dependent absorption spectra
A new ligand, bispyridin-2-ylmethyl-thiophen-2-ylmethylamine, 2ThDPA (1), was synthesized and its complexes of Cu(II) were isolated. When Cu(NO3)2 was used as the metal source, a mononuclear complex with the formula ...
Tsuji-Trost Cyclization of Disulfonamides: Synthesis of 12-Membered, 11-Membered, and Pyridine-Fused Macrocyclic Triamines
(ACS Omega, 2019)
Macrocyclic triamine disulfonamides can be synthesized by double Tsuji-Trost N-allylation reaction of open-chain disulfonamides with 2-alkylidene-1,3-propanediyl bis(carbonates). The previously used Atkins-Richman ...
Structural and Photophysical Properties of Visible- and Near-IR-Emitting Tris Lanthanide(III) Complexes Formed with the Enantiomers of N,N'-Bis(1-phenylethyl)-2,6-pyridinedicarboxamide
The enantiomers of N,N'-bis(1-phenylethyl)-2,6-pyridinedicarboxamide (L), namely, (R,R)-1, and (S,S)-1, react with LnIII ions to give stable [LnL3]3+ complexes in an anhyd. acetonitrile soln. and in the solid state, as ...
Uranyl Sensitization of Samarium(III) Luminescence in a Two-Dimensional Coordination Polymer
Heterometallic carboxyphosphonates UO22+/Ln3+ were prepd. from the hydrothermal reaction of uranyl nitrate, lanthanide nitrate (Ln = Sm, Tb, Er, Yb), and phosphonoacetic acid (H3PPA). Compd. 1, (UO2)2(PPA)(HPPA)2Sm(H2O)�2O ...