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Structural and Photophysical Properties of Visible- and Near-IR-Emitting Tris Lanthanide(III) Complexes Formed with the Enantiomers of N,N'-Bis(1-phenylethyl)-2,6-pyridinedicarboxamide
The enantiomers of N,N'-bis(1-phenylethyl)-2,6-pyridinedicarboxamide (L), namely, (R,R)-1, and (S,S)-1, react with LnIII ions to give stable [LnL3]3+ complexes in an anhyd. acetonitrile soln. and in the solid state, as ...
Uranyl Sensitization of Samarium(III) Luminescence in a Two-Dimensional Coordination Polymer
Heterometallic carboxyphosphonates UO22+/Ln3+ were prepd. from the hydrothermal reaction of uranyl nitrate, lanthanide nitrate (Ln = Sm, Tb, Er, Yb), and phosphonoacetic acid (H3PPA). Compd. 1, (UO2)2(PPA)(HPPA)2Sm(H2O)�2O ...
New k1,k1-benzoato-bridged complexes of Eu(III) and Tb(III) with a triazine-benzamide ligand
Two new complexes of Eu(III) and Tb(III) with the new ligand N,N',N''-(1,3,5-triazine-2,4,6-triyl)tribenza mide (TBZM) and benzoate (BA) have been isolated and crystallog. characterized. [Tb(BA)2(TBZM)(H2O)]2(CF3SO3)2�H3CN�2O, ...
A water-soluble Pybox derivative and its highly luminescent lanthanide ion complexes
A new water-soluble Pybox ligand, 1, has been synthesized and found to crystallize in the monoclinic P21/n space group with unit cell parameters a = 6.0936(1), b = 20.5265(4), c = 12.0548(2) �, ? = 90.614(1)o. In the ...
Unusual nitro-coordination of Eu(III) and Tb(III) with pyridinyl ligands
A new ligand family based on picoline, bipyridine and terpyridine containing a nitro moiety has been synthesized and its coordination and sensitization ability for lanthanide ions has been studied. Three new complexes were ...