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Diaquatris[4,4,4-trifluoro-3-oxo-1-(thiophen-2-yl)but-1-en-1-olato]neodymium(III) acetonitrile monosolvate
The title complex, [Nd(C8H4F3O2S)3(H2O)2]稢H3CN, consists of an NdIII ion surrounded by three 4,4,4-trifluoro-3-oxo-1-(thiophen-2-yl)but-1-en-1-olate ligands, coordinated through the O atoms, and two water mols. The Nd-O ...
Cadmium and Zinc Alloyed Cu-In-S Nanocrystals and Their Optical Properties
Cadmium (Cd)- and zinc (Zn)-alloyed copper杋ndium杝ulfide (Cu朓n朣 or CIS) nanocrystals (NCs) several nanometers in diameter were prepared using thermal decomposition methods, and the effects of Cd and Zn on optical properties, ...
Homobinuclear sulfato-bridged and mononuclear nitrato complexes of Cu(II) with thiophen-2-yl-dipicolylamine; structure and anion-dependent absorption spectra
A new ligand, bispyridin-2-ylmethyl-thiophen-2-ylmethylamine, 2ThDPA (1), was synthesized and its complexes of Cu(II) were isolated. When Cu(NO3)2 was used as the metal source, a mononuclear complex with the formula ...
Structural and Photophysical Properties of Visible- and Near-IR-Emitting Tris Lanthanide(III) Complexes Formed with the Enantiomers of N,N'-Bis(1-phenylethyl)-2,6-pyridinedicarboxamide
The enantiomers of N,N'-bis(1-phenylethyl)-2,6-pyridinedicarboxamide (L), namely, (R,R)-1, and (S,S)-1, react with LnIII ions to give stable [LnL3]3+ complexes in an anhyd. acetonitrile soln. and in the solid state, as ...
Uranyl Sensitization of Samarium(III) Luminescence in a Two-Dimensional Coordination Polymer
Heterometallic carboxyphosphonates UO22+/Ln3+ were prepd. from the hydrothermal reaction of uranyl nitrate, lanthanide nitrate (Ln = Sm, Tb, Er, Yb), and phosphonoacetic acid (H3PPA). Compd. 1, (UO2)2(PPA)(HPPA)2Sm(H2O)�2O ...
Synthesis, Lanthanide Coordination Chemistry, and Liquid-Liquid Extraction Performance of CMPO-Decorated Pyridine and Pyridine N-Oxide Platforms
Syntheses for a set of new ligands containing one or two carbamoylmethylphosphine oxide (CMPO) fragments appended to pyridine and pyridine N-oxide platforms are described. Molecular mechanics analyses for gas phase lanthanide? ...
New k1,k1-benzoato-bridged complexes of Eu(III) and Tb(III) with a triazine-benzamide ligand
Two new complexes of Eu(III) and Tb(III) with the new ligand N,N',N''-(1,3,5-triazine-2,4,6-triyl)tribenza mide (TBZM) and benzoate (BA) have been isolated and crystallog. characterized. [Tb(BA)2(TBZM)(H2O)]2(CF3SO3)2�H3CN�2O, ...
para-Derivatized Pybox ligands as sensitizers in highly luminescent Ln(III) complexes
New complexes of pyridine-bis(oxazoline) derivatized with -H, -OMe and -Br at the para position of the pyridine ring with Eu(III) and Tb(III) have been isolated. These are highly luminescent in the solid state, regardless ...