University of Nevada, Reno
Chemistry - Faculty Research
Browse by
Recent Submissions
-
Charging Processes in Electroactive C60/Pd Films: Effect of Solvent and Supporting Electrolyte
(1999)The electrochem. properties of solid films deposited on an electrode surface by simultaneous electrochem. redn. of C60 and palladium(II) acetate trimer in an acetonitrile/toluene mixt. have been studied using cyclic ... -
Crystallographic Characterization of the Structure of the Endohedral Fullerene [Er2@C82 Isomer I] with Cs Cage Symmetry and Multiple Sites for Erbium along a Band of Ten Contiguous Hexagons
(2002)The structure of one of the three previously sepd. isomers of {Er2@C82} was detd. through a single-crystal x-ray structure detn. of the noncovalent adduct, {Er2@C82 Isomer I}.cntdot.{CoII(OEP)}.cntdot.1.4(C6H6).cntdot.0.3(CHCl3). ... -
Electrochemical Studies of C60/Pd Films Formed by the Reduction of C60 in the Presence of Palladium(II) Acetate Trimer. Effects of Varying C60/Pd(II) Ratios in the Precursor Solutions
(2000)Cyclic voltammetric studies of the electrochem. formation and redox properties of C60/Pd films are reported. Films used in this work are generated under multicyclic scans in an acetonitrile/toluene (1:4, vol./vol.) mixt. ... -
First Unsymmetrical Bisfullerene, C121: Evidence for the Presence of Both Homofullerene and Methanofullerene Cages in One Molecule
(2001)The authors report the isolation and characterization of the bisfullerene C121, the 1st all-carbon mol. to contain a homofullerene (also called a fulleroid) cage. This unsym. isomer of C121, along with a sym. isomer of ... -
Recent advances in the electrochemistry of fullerene/transition metal co-polymers
(2000)A review, with 20 refs. on formation and properties of the thin C60/transition metal layers is presented. These films can be prepd. by electroredn. from soln. contg. the fullerene and different metal precursors. So far, ... -
The influence of electroactive solutes on the properties of electrochemically formed fullerene C60-based films
(2003)A study of simple redox solutes, ferrocene, N,N,N',N'-tetramethyl-1,4-phenylenediamine, decamethylferrocene, bis(i-propylcyclopentadienyl)iron(II), [Ru(phen)3](ClO4)2, [Fe(bpy)3](ClO4)2, [Co(bpy)3](ClO4)2, and iodine has ... -
Electrochemical properties of MC60 (M=Pd, Pt) covered electrodes
(1999)The formation of electroactive films contg. [60]fullerene and Pd or Pt was obsd. for solns. with the C60 and different metal complexes, Pd(PhCN)2Cl2, [Pd(CH3CO2)2]3, Pd(CH3CO2)2, [Pt(.mu.-Cl)Cl(C2H4)]2, cis-PtCl2(py)2, ... -
Redox-active films formed by electrochemical reduction of solutions of C60 and platinum complexes
(2002)Electroredn. of a toluene-acetonitrile (4:1 vol./vol.) soln. of C60 and cis-Pt(py)2Cl2 in the presence of 0.10M tetra(n-butyl)ammonium perchlorate as supporting electrolyte produces a black, redox active film that coats ... -
Isolation and structural characterization of the endohedral fullerene Sc3N@C78
(2001)The endohedral fullerene Sc3N@C78 was prepd., isolated and characterized by its 13C NMR, UV/Vis and mass spectra. Black crystals of Sc3N@C78.cntdot.[Co(oep)].cntdot.1.5C6H6.cntdot.0.3CHCl3 were obtained (H2oep = ... -
Electronic Interactions in a New Fullerene Dimer: C122H4, with Two Methylene Bridges
(2000)The isolation of a new fullerene dimer, C122H4, and its structural characterization by 13C NMR and 1H NMR spectroscopy and by UV/vis and IR spectroscopy are reported. The structure of this dimer consists of two fullerene ... -
Ligand Design for Luminescent Lanthanide-Containing Metallopolymers
(2016)The isolation of emissive materials with lanthanide ions is a topic of interest for imaging, display, and sensing applications, and it requires tuning of the electronics of the systems, such that, during the process of ... -
Luminescence and non-linear optical properties in copper(I) halide extended networks
(2016)The syntheses, structures, and luminescence properties of a series of copper(I) halide coordination polymers, prepared with mono- and bidentate N-heteroaromatic ligands, are reported. These metal–organic coordination ... -
Tuning the structural and lanthanide luminescence properties of macrocyclic tetraiminodiphenolate europium(III) complexes
(2016)The synthesis, structural characterization, and luminescence properties of two novel macrocyclic tetraiminodiphenolate europium(III) complexes are reported. The macrocyclic ligands studied bind the lanthanide through four ... -
Isolation and Crystallographic Characterization of ErSc2N@C80: an Endohedral Fullerene Which Crystallizes with Remarkable Internal Order
(2000)The ErnSc3-nN@C80 (n = 0-3) family of four endohedral fullerenes was prepd. by vaporization of graphite rods packed with 2% Sc2O3/3% Er2O3/95% graphite powder in a Kratschmer-Huffman fullerene generator under dynamic flow ... -
Photophysical properties of asymmetric and water-soluble dinuclear lanthanide complexes of poly glycol chain functionalized-benzoic acid derivative: experimental and theoretical approaches
(2016)New water-soluble lanthanide complexes with a poly glycol chain (朞EtOEtOEtOMe) functionalized benzoic acid derivative ligand were synthesized and photophysically characterized. The results indicate a formation of an ... -
Phenylthiophene-dipicolinic acid-based emitters with strong solution blue and solid state green emission
(2006)The synthesis and characterization of highly efficient blue emitting phenyl?thiophene compounds derivatized with dipicolinic acid bis(diethylamide) and dipicolinic acid diethyl ester 1, 2, and 3 are reported. Quantum yields ... -
Pyrenes, Peropyrenes, and Teropyrenes: Synthesis, Structures, and Photophysical Properties
(2016)The design of a relatively simple and efficient method to extend the ?-conjugation of readily available aroms. in one-dimension is of significant value. In this paper, pyrenes, peropyrenes, and teropyrenes were synthesized ... -
2-Chloro-5-nitrobenzoato complexes of Eu(III) and Tb(III) - A 1D coordination polymer and enhanced solution luminescence
(2006)A luminescent 2-chloro-5-nitrobenzoic acid derivative of Eu(III) with a columnar structure has been isolated and characterized. This compound shows red emission in the solid state. Solutions of the ligand and Eu(III) in ... -
Nitro-functionalization and quantum yield of emission of Eu(III) and Tb(III) benzoic acid complexes
(2006)In our pursuit of luminescent lanthanide ion-based coordination polymers, we have isolated several complexes with nitrobenzoic acid ligands and characterized these by X-ray crystallography and luminescence spectroscopy. ...
RSS 1.0