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Electrochemical Studies of C60/Pd Films Formed by the Reduction of C60 in the Presence of Palladium(II) Acetate Trimer. Effects of Varying C60/Pd(II) Ratios in the Precursor Solutions
Cyclic voltammetric studies of the electrochem. formation and redox properties of C60/Pd films are reported. Films used in this work are generated under multicyclic scans in an acetonitrile/toluene (1:4, vol./vol.) mixt. ...
Charging Processes in Electroactive C60/Pd Films: Effect of Solvent and Supporting Electrolyte
The electrochem. properties of solid films deposited on an electrode surface by simultaneous electrochem. redn. of C60 and palladium(II) acetate trimer in an acetonitrile/toluene mixt. have been studied using cyclic ...
Structure and properties of C60-Pd films formed by electroreduction of C60 and palladium(II) acetate trimer: evidence for the presence of palladium nanoparticles
The compn., surface morphol., structure, and electrochem. properties of thin solid films of the polymer, C60-Pd, were studied by Raman spectroscopy, XPS, powder X-ray diffraction (XRD), and energy dispersive X-ray fluorescence ...
The influence of electroactive solutes on the properties of electrochemically formed fullerene C60-based films
A study of simple redox solutes, ferrocene, N,N,N',N'-tetramethyl-1,4-phenylenediamine, decamethylferrocene, bis(i-propylcyclopentadienyl)iron(II), [Ru(phen)3](ClO4)2, [Fe(bpy)3](ClO4)2, [Co(bpy)3](ClO4)2, and iodine has ...
Redox-active films formed by electrochemical reduction of solutions of C60 and platinum complexes
Electroredn. of a toluene-acetonitrile (4:1 vol./vol.) soln. of C60 and cis-Pt(py)2Cl2 in the presence of 0.10M tetra(n-butyl)ammonium perchlorate as supporting electrolyte produces a black, redox active film that coats ...
Electrochemical properties of MC60 (M=Pd, Pt) covered electrodes
The formation of electroactive films contg. fullerene and Pd or Pt was obsd. for solns. with the C60 and different metal complexes, Pd(PhCN)2Cl2, [Pd(CH3CO2)2]3, Pd(CH3CO2)2, [Pt(.mu.-Cl)Cl(C2H4)]2, cis-PtCl2(py)2, ...
Recent advances in the electrochemistry of fullerene/transition metal co-polymers
A review, with 20 refs. on formation and properties of the thin C60/transition metal layers is presented. These films can be prepd. by electroredn. from soln. contg. the fullerene and different metal precursors. So far, ...