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Isolation and structural characterization of the endohedral fullerene Sc3N@C78
AuthorOlmstead, Marilyn M.
de Bettencourt-Dias, Ana
Duchamp, James C.
Dorn, Harry C.
Balch, Alan L.
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he unfavorable D3h isomer of the C78 fullerene cage is present in Sc3N@C78, an endohedral fullerene which has been prepared by the trimetallic nitride template process. The crystal structure of the fullerene–porphyrin adduct Sc3N@C78⋅[Co(oep)]⋅1.5 C6H6⋅0.3 CHCl3 (oep=octaethylporphyrin) shows that the scandium atoms are located over the centers of the [6,6] ring junctions of pyracylene patches on the inner surface of the fullerene (see picture).