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Synthesis, Characterization, and Reactivity of the Half-Sandwich Ruthenium (II) Hydride Complexes of 1,3,5-Triaza-7-Phosphaadamantane
A new water-soluble bis-PTA ruthenium (II) hydride complex, IndRu(PTA)2H, is obtained by conversion of the mixed-phosphine ruthenium complex IndRu(PTA)(PPh3)Cl into IndRu(PTA)(PPh3)H followed by addition of 1,3,5-triaza- ...